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Spectrophotometric Determination of Gemifloxacin Mesylate, Moxifloxacin.HCl and Gatifloxacin Sesquihydrate in Pure and in Pharmaceutical Preparations

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Last updated: 22 Jan 2023

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Abstract

SIMPLE, rapid and sensitive spectrophotometric method was developed for the determination of gemifloxacin mesylate (GMF), moxifloxacin.HCl (MXF) and gatifloxacin sesquihydrate (GAF) in pure and pharmaceutical preparation. This method is based on ion pair formation reaction between GMF, MXF and GAF and rosebengal indicator in universal buffer of pH 5.The formed ion pair is measured at λmax = 575 nm. All optimum conditions are established. The calibration graphs are rectilinear at concentration ranges 9.71 – 53.40, 8.758 – 52.55 and 8.048– 48.29 μg ml-1 for GMF, MXF and GAF, respectively. The sandell sensitivity (S) = 0.0263 , 0.0244 and 0.0263 μg cm-2 , molar absorptivity = 1.861x 104 , 1.835x 104 and 1.561x 104 L mol-1 cm-1 , correlation coefficient 0.9998 and LOD = 01.90, 1.607 and 1.876 μg ml-1 and LOQ = 05.74, 0.2036 and 5.684 μg ml-1 are calculated for GMF, MXF and GAF, respectively. The values of SD are = 0.0218 - 0.0297, 0.02 - 0.0377 and 0.0216 - 0.0282 and RSD are = 0.0554 - 0.3075, 0.0380 - 0.4344 and 0.0537 - 0.3497 % for GMF, MXF and GAF. The method is applied for the assay of investigated three drugs in pharmaceutical dosage forms. The results are in good agreement with those obtained by the official methods

DOI

10.21608/ejchem.2015.1028

Keywords

Gemifloxacin mesylate, Moxifloxacin. HCl, Gatifloxacin sesquihydrate, Ion pair formation and Spectrophotometry

Volume

58

Article Issue

3

Related Issue

242

Issue Date

2015-06-01

Receive Date

2014-12-14

Publish Date

2015-06-30

Page Start

349

Page End

364

Print ISSN

0449-2285

Online ISSN

2357-0245

Link

https://ejchem.journals.ekb.eg/article_1028.html

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https://ejchem.journals.ekb.eg/service?article_code=1028

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10

Type Code

292

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

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Article

Created At

22 Jan 2023