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Fenton Oxidation Process of Refractory Organics in Gas Processing Wastewater

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Last updated: 01 Jan 2025

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Abstract

IN THE CURRENT research, treatment of gas-associated wastewater (3,100 m3/d) from a gas production company located at Alexandria was carried out. The produced wastewater was found to be contaminated with high organic and inorganic pollutants, characterized by high COD (chemical oxygen demand) 55000 mg/L, low BOD (biochemical oxygen demand) 9500 mg/, TSS (total suspended solids) 385 mg/L and total phenols of 0.8 mg/L. The BOD/COD ratio of 0.17 proves that wastewater has hazardous organics that are hardly biodegradable. Due to the low TSS concentration, conventional coagulation precipitation method is not considered adequate.  A Fenton reagent [Fe2+/ H2O2] is proposed for degradation of existing soluble organics in the wastewater. Optimum operating conditions were: H2O2 in concentration of 1.6 M/L (one Stoichiometry with COD), 80 mM/L of Fe2+ ions, at pH around 3 and optimal time of 30 minutes. A corresponding residual concentration of COD and BOD were 11000 and 4000 mg/L and a complete removal of phenols. Results concluded that, Fenton reagent was found suitable to improve the biodegradability of the raw gas processingwastewater, BOD/COD increased from 0.17 to 0.36 and a complete removal of phenols has been achieved, making it feasible to be treated biologically in effective manner.

DOI

10.21608/ejchem.2016.957

Keywords

Gas, Dehydration, Wastewater, Refractory, Organics, Removal and Fenton

Volume

59

Article Issue

2

Related Issue

217

Issue Date

2016-04-01

Receive Date

2016-01-11

Publish Date

2016-04-30

Page Start

241

Page End

252

Print ISSN

0449-2285

Online ISSN

2357-0245

Link

https://ejchem.journals.ekb.eg/article_957.html

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https://ejchem.journals.ekb.eg/service?article_code=957

Order

7

Type Code

292

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

MainTitle

Fenton Oxidation Process of Refractory Organics in Gas Processing Wastewater

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Article

Created At

22 Jan 2023