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1503

γ-Ray Induced Metastable Defects in Mn-Doped Lead-Phosphate Glass

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Last updated: 22 Jan 2023

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Abstract

 PbO-P2O5+ xMnO2 (02 on structural and optical properties of glasses have been investigated using different characterization techniques. The effect of both glass composition and MnO2 content on the generation of radiation-induced defects has been investigated. The intensity and the position of the induced bands are found to depend on the type and composition of glass, concentration of the dopant and also on the irradiation dose. Experimental results indicate that the undoped glass reveals before irradiation strong and broad ultraviolet absorption which is related to the co-sharing of absorption due to both trace iron impurities and lead ions (Pb2+). The band gap energy is found to decrease with the increasing content of MnO2 in the glasses, while different irradiation doses showed remarkable effect on the band gap which decreases to semi conducting range. The effect of gamma irradiation also takes place, the band gap decreases from 4.15 to 2.9 eV and from 3.84 to 2.8 for indirect transition for both G1 and G4 respectively also for all glass systems.

DOI

10.21608/ejrsa.2013.1503

Keywords

Lead-phosphate glass, gamma-irradiation, optical absorption, optical energy gap

Volume

26

Article Issue

1

Related Issue

321

Issue Date

2013-12-01

Receive Date

2013-09-15

Publish Date

2013-12-31

Page Start

147

Page End

164

Print ISSN

1110-0303

Online ISSN

2314-8527

Link

https://ejrsa.journals.ekb.eg/article_1503.html

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https://ejrsa.journals.ekb.eg/service?article_code=1503

Order

11

Type

Original Article

Type Code

136

Publication Type

Journal

Publication Title

Egyptian Journal of Radiation Sciences and Applications

Publication Link

https://ejrsa.journals.ekb.eg/

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Article

Created At

22 Jan 2023