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52032

Redistribution and Desorption Kinetics of Some Heavy Metals in Biosolids Treated Soils Amended with Water Treatment Residual Nanoparticles

Article

Last updated: 01 Jan 2025

Subjects

-

Tags

Aquatic and terrestrial environment

Abstract

The study was designed to demonstrate the effect of water treatment residual naoparticles amendments for 0.3%  biosolids treated calcareous and sandy soils on Cu, Pb, and Ni fractions change and release during 60 days incubation period; included five wetting drying cycles regime. The redistribution of studied metals fractions for control soil (0%WTR) depended  on soil and metal type. There was a pronounced decrease in metal-residual fraction at the end of the incubation period (60 days); while other fractions were occupied with these residual fraction- released metals. Application ofnWTR to both soils substantially reduced the non-residual fractions (NORS) of Cu and Ni and simultaneously increased residual (RS) both metals fractions. Furthermore,both Pb-oxides and RS fractions were increased as a result of nWTR addition. The metals forms transformation for nWTR amended soils as the incubation time prolonged from 30 to 60 days was studied. The Cu-forms transformation remained relatively unalteredwith slightly increase of RS Cu versus decrease of exchangeable and carbonate Cu. With respect to Pb and Ni, residual fraction was increased significantly and this increase was arisen from either the decrease of all fractions of Ni- NORS or Pb-organic fraction. The amount of desorbed Cu, Pb, and Ni from both soils using DTPA extraction was significantly decreased after application of nWTR within the five wetting drying cycles. All the kinetic data were well expressed using both intraparticle diffusion and Elovich models due to the high coefficient of determination (R2) and low standard error (SE) values. The final results indicate the ability of nWTR to reduce heavy metals mobility in biosolid treated calcareous and sandy soils.  
 

DOI

10.21608/asejaiqjsae.2019.52032

Keywords

Biosolid, water treatment residual naoparticles, incubation period, fractionation, desorption kinetic

Authors

First Name

Mohamed L.

Last Name

Moharem

MiddleName

-

Affiliation

Regional center for Food and Feed, Agricultural Research center, Alexandria, Egypt

Email

mlmoharem@hotmail.com

City

-

Orcid

0000-00002-6563-785x

Volume

40

Article Issue

July-September

Related Issue

6935

Issue Date

2019-08-01

Receive Date

2019-08-23

Publish Date

2019-09-30

Page Start

487

Page End

501

Print ISSN

1110-0176

Online ISSN

2536-9784

Link

https://asejaiqjsae.journals.ekb.eg/article_52032.html

Detail API

https://asejaiqjsae.journals.ekb.eg/service?article_code=52032

Order

9

Type

Original Article

Type Code

53

Publication Type

Journal

Publication Title

Alexandria Science Exchange Journal

Publication Link

https://asejaiqjsae.journals.ekb.eg/

MainTitle

Redistribution and Desorption Kinetics of Some Heavy Metals in Biosolids Treated Soils Amended with Water Treatment Residual Nanoparticles

Details

Type

Article

Created At

22 Jan 2023