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2863

Removal of Oxamyl in Soil by Different Treatments

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Last updated: 01 Jan 2025

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Tags

Plant pest management

Abstract

The remediation of the oxamyl pesticide, applied, at a rate of 50 µg/gm soil and amended with different materials namely, Tergitol NP9 (nonionic surfactant), charcoal, lorandeat and iron fillings at rate of 300, 250, 250 and 300 Kg/Fadden, respectively, was investigated. The oxamyl residue levels in loamy sand was extracted at different time intervals after treatment based on the solid phase extraction (SPE) with methanol and then analyzed by HPLC. Only the peak corresponding to oxamyl was observed in the chromatogram and no intermediate metabolites  could be detected. At the end of the experiment (21 days), the dissipation percentage of oxamyl reached about 88, 78, 73 and 72% in soil amended with NP-9, Fe, lorandeat and charcoal, respectively. The rate of disappearance was 2 times higher than in unamended-soil, while Fe, lorandeat and charcoal  enhanced the dissipation rate by 1.77, 1.65 and 1.61 times, respectively. The disappearance rate constants and half-life values of the compound were obtained from the exponential decay equations. The decomposition of oxamyl in the control, charcoal and lorandeat followed the first order kinetics with t1/2 of about 22.08, 13.8 and 13.2 days. On the other hand, a biphasic model was assumed to explore the disappearance of oxamyl in soil amended with NP-9 and Fe where the rate of disappearance in the first phase was faster than the second phase. This is clearly reflected in the half-life (t0.5) values for the first and second phases, where the t0.5 values of oxamyl ranged from 3.3 to 12.7 and 6.5 to 15.6 days, respectively. The results demonstrated that using NP-9, Fe, charcoal and lorandeat may offer an efficient remediation treatment for oxamyl-polluted soil.

DOI

10.21608/asejaiqjsae.2015.2863

Keywords

(soil, Removal, Charcoal, lorandeat, Tergitol NP-9, iron fillings, oxamyl)

Authors

First Name

Khaled A.

Last Name

Osman

MiddleName

-

Affiliation

Department of Pesticide Chemistry & Technology, Faculty of Agriculture, Alexandria University, Alexandria, P.O. Box 21545, Egypt

Email

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City

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Orcid

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First Name

Ahmed S.

Last Name

El-Bakary

MiddleName

-

Affiliation

Department of Pesticide Chemistry & Technology, Faculty of Agriculture, Alexandria University, Alexandria, P.O. Box 21545, Egypt

Email

-

City

-

Orcid

-

First Name

Nabila A.

Last Name

Saber

MiddleName

-

Affiliation

Department of Pesticide Chemistry & Technology, Faculty of Agriculture, Alexandria University, Alexandria, P.O. Box 21545, Egypt

Email

-

City

-

Orcid

-

First Name

A.H

Last Name

El-Sebai

MiddleName

-

Affiliation

Department of Pesticide Chemistry & Technology, Faculty of Agriculture, Alexandria University, Alexandria, P.O. Box 21545, Egypt

Email

-

City

-

Orcid

-

First Name

M. SH.

Last Name

Salama

MiddleName

-

Affiliation

Department of Pesticide Chemistry & Technology, Faculty of Agriculture, Alexandria University, Alexandria, P.O. Box 21545, Egypt

Email

-

City

-

Orcid

-

Volume

36

Article Issue

April-June

Related Issue

529

Issue Date

2015-06-01

Receive Date

2015-05-13

Publish Date

2015-06-30

Page Start

141

Page End

146

Print ISSN

1110-0176

Online ISSN

2536-9784

Article File

ASEJAIQJSAE_Volume 36_Issue April-June_Pages 141-146.pdf

PDF . 178.2kB

Link

https://asejaiqjsae.journals.ekb.eg/article_2863.html

Detail API

https://asejaiqjsae.journals.ekb.eg/service?article_code=2863

Order

5

Type

Original Article

Type Code

53

Publication Type

Journal

Publication Title

Alexandria Science Exchange Journal

Publication Link

https://asejaiqjsae.journals.ekb.eg/

MainTitle

Removal of Oxamyl in Soil by Different Treatments

Details

Type

Article

Created At

22 Jan 2023