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369573

Kinetics of leaching process of Uranium from EL-Missikat shear zone Eastern Desert, EGYPT

Article

Last updated: 29 Dec 2024

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Abstract

The leaching process of uranium- REE ore from El-Missikat in a sulfuric 
acid solution using hydrogen peroxide as an oxidant was investigated. 
The leaching condition temperature, hydrogen peroxide concentration, 
sulfuric acid concentration, contact time, particle size, solid-liquid ratio 
and agitation rate were studied. The optimum process operating 
parameters were: ore particle size 74 µm; sulfuric acid concentration 2.5 
M; contact time 240 min; solid-liquid ratio 1:2; H2O2 concentration 0.5 
M and agitation rate 600 rpm at temperature 25°C. The leaching
efficiency of REE was about 70%, while the uranium leaching efficiency 
was about 95%. The experimental data were well interpreted with a 
shrinking core model with diffusion control through a porous product 
layer. The leaching process follows the kinetic model: 
1-3 (1-X) 2/3 + 2 (1-X) = k1t with an apparent activation energy of 13.16 
kJ/mole.

DOI

10.21608/jbes.2014.369573

Keywords

Leaching, Uranium, REE, Shrinking core model, Kinetics, Diffusion

Authors

First Name

M. A.

Last Name

Moussa

MiddleName

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Affiliation

Chemistry Department, Faculty of Science, Benha University, Egypt

Email

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City

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Orcid

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First Name

A. M.

Last Name

Daher

MiddleName

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Affiliation

Nuclear Materials Authority, P.O. Box 530, El Maadi, Cairo, Egypt

Email

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City

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Orcid

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First Name

S. A.

Last Name

Omar

MiddleName

-

Affiliation

Nuclear Materials Authority, P.O. Box 530, El Maadi, Cairo, Egypt

Email

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City

-

Orcid

-

First Name

Y. M.

Last Name

Khawassek

MiddleName

-

Affiliation

Nuclear Materials Authority, P.O. Box 530, El Maadi, Cairo, Egypt

Email

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City

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Orcid

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First Name

E. A.

Last Name

Haggag

MiddleName

-

Affiliation

Nuclear Materials Authority, P.O. Box 530, El Maadi, Cairo, Egypt

Email

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City

-

Orcid

-

First Name

E.A.

Last Name

Gawad

MiddleName

-

Affiliation

Nuclear Materials Authority, P.O. Box 530, El Maadi, Cairo, Egypt

Email

-

City

-

Orcid

-

Volume

1

Article Issue

2

Related Issue

49423

Issue Date

2014-04-01

Receive Date

2024-07-27

Publish Date

2014-04-01

Page Start

65

Page End

75

Print ISSN

2536-9202

Online ISSN

2356-6388

Link

https://jbes.journals.ekb.eg/article_369573.html

Detail API

https://jbes.journals.ekb.eg/service?article_code=369573

Order

369,573

Type

Original Article

Type Code

3,063

Publication Type

Journal

Publication Title

Journal of Basic and Environmental Sciences

Publication Link

https://jbes.journals.ekb.eg/

MainTitle

Kinetics of leaching process of Uranium from EL-Missikat shear zone Eastern Desert, EGYPT

Details

Type

Article

Created At

21 Dec 2024