Beta
ManageSearchChatDiscover
124647

Polymer Complexes.LVII. Structures of Supramolecular Assemblies of Polymer Complexes of Dioxouranium(VI) with some Substituted Allyl Azodyes.

Article

Last updated: 04 Jan 2025

OverviewSimilar Items

Subjects

-

Tags

Mathematics and Engineering Physics

Abstract

Novel five polymeric dioxouranium(VI) of bidentate allyl azo homopolymer compounds derived from allyl rhodanine were prepared for the first time. The infrared spectra of the samples were recorded and their fundamental vibrational wave number was obtained. The resulting polymeric uranyl complexes have been characterized on the basis of elemental analyses, conductance and spectral (IR, NMR, and electronic spectra) data. The nature of bonding has been further discussed based on IR spectral data. The theoretical aspects are described in terms of the well-known theory of 5d-4f transitions. The coordination geometries and electronic structures are determined from a framework for the modeling of novel polymer complexes. The values of us of the prepared polymer complexes containing UO22+ were successfully used to calculate the force constant, Fuo (In mdyn/A) and the bond length Ruo (in Ao) of the U-O bond. Wilson's, matrix method, Badger's formula, and Jones and El-Sonbati equations were used to calculate the U-O bond distances from the values of the stretching and interaction force constants. The most probable correlation between U-O force constant to U-O bond distance were satisfactorily discussed in term of "Badger's rule", "Jones" and "El-Sonbati equations". The Hammett constant is also discussed.
 

DOI

10.21608/bfemu.2020.124647

Keywords

Supramolecular structures, UO22,* azo, polymeric complexes, McGlynn, Badger's models, Jones and El-Sonbati equations

Authors

First Name

A.

Last Name

El-Sonbati

MiddleName

z.

Affiliation

Chemistry Department, Faculty of Science (Demiatta), Mansoura University, Demiatta, Egypt.

Email

elsonbatisch@yahoo.com

City

-

Orcid

-

First Name

M.

Last Name

Diab

MiddleName

A.

Affiliation

Chemistry Department, Faculty of Science (Demiatta), Mansoura University, Demiatta,

Email

-

City

-

Orcid

-

First Name

A.

Last Name

Belal

MiddleName

A. M.

Affiliation

Chemistry Department., Faculty of Science Port Said University., Egypt.

Email

-

City

-

Orcid

-

First Name

M.

Last Name

Attallah

MiddleName

E.

Affiliation

Chemistry Department., Faculty of Science (Demiatta) Mansoura University., Demiatta., Egypt.

Email

-

City

Demiatta

Orcid

-

Volume

35

Article Issue

2

Related Issue

18139

Issue Date

2010-06-01

Receive Date

2010-04-19

Publish Date

2020-11-21

Page Start

1

Page End

11

Print ISSN

1110-0923

Online ISSN

2735-4202

Article File

BFEMU_Volume 35_Issue 2_Pages 1-11.pdf

PDF . 1.0MB

Link

https://bfemu.journals.ekb.eg/article_124647.html

Detail API

https://bfemu.journals.ekb.eg/service?article_code=124647

Order

9

Type

Research Studies

Type Code

1,205

Publication Type

Journal

Publication Title

MEJ. Mansoura Engineering Journal

Publication Link

https://bfemu.journals.ekb.eg/

MainTitle

Polymer Complexes.LVII. Structures of Supramolecular Assemblies of Polymer Complexes of Dioxouranium(VI) with some Substituted Allyl Azodyes.

Details

Type

Article

Created At

22 Jan 2023