Abstract: This paper presents a novel method of classifying speech phonemes. Four hybrid techniques based on the acoustic-phonetic approach and pattern recognition approach are used to emphasize the principle idea of this research. The first hybrid model is constructed of fixed state, structured Hidden Markov Model, Gaussian Mixture, Mel scaled Best Tree Image, Convolution Neural network, Vector Quantization (FS-HMM-GM-MBTI-CNN-VQ). The second hybrid model is constructed of variable state, dynamically structured Hidden Markov Model, Gaussian Mixture, Mel scaled Best Tree Image, Convolution Neural network, Vector Quantization (VS-HMM-GM-MBTI-CNN-VQ). The third hybrid model is constructed of fixed state, structured Hidden Markov Model, Gaussian Mixture, Mel scaled Best Tree Image, Convolution Neural network (FS-HMM-GM-MBTI-CNN). The fourth hybrid model is constructed of variable state, dynamically structured Hidden Markov Model, Gaussian Mixture, Mel scaled Best Tree Image, Convolution Neural network (VS-HMM-GM-MBTI-CNN). TIMIT database is used in this paper. All phones are classified into five classes and segregated into Vowels, Plosives, Fricatives, Nasals, and Silences. The results show that using (VS-HMM-GM-MBTI-CNN-VQ) is an available method for classification of phonemes, with the potential for use in applications such as automatic speech recognition and automatic language identification. Competitive results are achieved especially in nasals, plosives, and silence high successive rates than others.