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209849

Preliminary study of the Armored Door at Al-Zaher Barqūq's Mosque, Condition Assessment, and Previous Conservation Campaigns

Article

Last updated: 01 Jan 2025

Subjects

-

Tags

Analytical chemistry

Abstract

Copper alloys-plaques used for the door of Barqūq's Mosque exhibited significant corrosion processes. Thorough chemical analyses revealed a diversity of metals and minerals in the alloy. This paper presents a case study related to the armored door's chemical structure and crafting techniques, along with its degradation and previous conservation campaigns. The surface morphology of the laminated door was examined by both stereomicroscope and scanning electron microscopy (SEM).
The microstructural analysis is done by scanning electron microscopy-energy dispersive X-ray spectrometry (EDXS). Copper-iron corrosion products collected from the surface were examined using Raman spectroscopy. Fourier-transform infrared spectroscopy (FTIR) was used to characterize of the adhesive material used to fix the inlaid silver. Results revealed that quaternary alloy (copper, tin, lead, and zinc) were mainly used to manufacture the armored door inlaid with gold, silver, and red copper. A disproportionate percentage of chloride and sulfur ions were detected in the active corroded products growth on copper-based alloys and inlays. These are the cause of morphological alterations. Recent routine techniques performed for conservation treatments of the plaques and inlaid silver. The protection system was done by benzotriazole, incralack followed by a thin layer of Boston wax.

DOI

10.21608/ejchem.2021.109268.4981

Keywords

Al-Zaher Barqūq's Mosque, Armored Door, Copper-Alloy Sheet, Corrosion, examination, Analyses, conservation

Authors

First Name

Saleh

Last Name

Ahmed

MiddleName

Mohammed

Affiliation

Restoration and Conservation department, Faculty of Archaeology, Fayoum University

Email

sms02@fayoum.edu.eg

City

Giza

Orcid

-

First Name

Ragab

Last Name

Abou Elhassan

MiddleName

-

Affiliation

Restoration and Conservation department, Faculty of Archaeology and Tourism Guidance, Misr University for Science & Technology (MUST)

Email

-

City

-

Orcid

-

Volume

65

Article Issue

7

Related Issue

31861

Issue Date

2022-07-01

Receive Date

2021-12-03

Publish Date

2022-07-01

Page Start

669

Page End

685

Print ISSN

0449-2285

Online ISSN

2357-0245

Link

https://ejchem.journals.ekb.eg/article_209849.html

Detail API

https://ejchem.journals.ekb.eg/service?article_code=209849

Order

65

Type

Original Article

Type Code

297

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

MainTitle

Preliminary study of the Armored Door at Al-Zaher Barqūq's Mosque, Condition Assessment, and Previous Conservation Campaigns

Details

Type

Article

Created At

22 Jan 2023