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73260

Inhibition of Aluminum Alloy 7025 in Acid Solution Using Sulphamethoxazole

Article

Last updated: 01 Jan 2025

Subjects

-

Tags

Environmental chemistry

Abstract

Corrosion behavior of 7025 aluminum alloy was investigated in hydrochloric acid (pH=1) containing 0.6 mol.〖dm〗^(-3) NaCl in the existence and absence of diverse concentrations of sulphamethoxazole as environmentally friendly corrosion inhibitor over the temperature range (298-313)K. Electrochemical polarization method using potentiostatic technique was employed. The inhibition efficiency has been raised with increased sulphamethoxazole concentration but lessened at temperature increases. The highest efficiency value was 96.5 of 298 K and 2× 〖10〗^(-4) mol.〖dm〗^(-3) concentration of sulphamethoxazole. The sulphamethoxazole adsorption was agreed with Langmuir adsorption isotherm. Some thermodynamic parameter (〖∆G〗_ads ) and activation energy (E_a ) were determined to demonstrate the process of corrosion inhibiting. The kinetic parameters were calculated using Arrhenius equation. An appropriate mechanism has been suggested for aluminum corrosion in acidic medium. The results show that sulphamethoxazole is a mixed type inhibitor. The surface morphology of uninhibited and inhibited samples was investigated using optical microscope.

DOI

10.21608/ejchem.2020.15541.1942

Keywords

Corrosion inhibition, Aluminum, Sulphamethoxazole, Free energy, adsorption mechanism

Authors

First Name

Zainab W.

Last Name

Ahmed

MiddleName

-

Affiliation

Department of Chemistry, College of Education for Pure Science- Ibn Al-Haitham, University of Baghdad, Baghdad, Iraq

Email

-

City

-

Orcid

-

First Name

Juman

Last Name

Naser

MiddleName

-

Affiliation

Department of chemistry,College of education, University of Baghdad, Baghdad, Iraq

Email

juman_chem@yahoo.com

City

-

Orcid

0000-0003-2319-5384

First Name

Azhar

Last Name

Farooq

MiddleName

-

Affiliation

Department of Chemistry, College of Education for Pure Science- Ibn Al-Haitham, University of Baghdad, Baghdad, Iraq

Email

-

City

-

Orcid

-

Volume

63

Article Issue

10

Related Issue

17778

Issue Date

2020-10-01

Receive Date

2019-08-01

Publish Date

2020-10-01

Page Start

3,703

Page End

3,711

Print ISSN

0449-2285

Online ISSN

2357-0245

Link

https://ejchem.journals.ekb.eg/article_73260.html

Detail API

https://ejchem.journals.ekb.eg/service?article_code=73260

Order

10

Type

Original Article

Type Code

297

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

MainTitle

Inhibition of Aluminum Alloy 7025 in Acid Solution Using Sulphamethoxazole

Details

Type

Article

Created At

22 Jan 2023